Here are some examples where "as" functions as a root word:
* Ascend (to move upwards)
* Ascent (the act of moving upwards)
* Ascertain (to find out for certain)
* Ascribe (to attribute something to a particular cause)
* Assail (to attack violently)
* Assemble (to gather together)
* Assert (to state strongly)
* Assiduous (showing great care and perseverance)
* Assist (to help)
* Associate (to connect with)
Let me know if you'd like more examples!