General synonyms:
* Blank
* Impassive
* Stoic
* Apathetic
* Emotionless
* Devoid of emotion
* Unresponsive
* Unreadable
Synonyms emphasizing lack of movement:
* Still
* Rigid
* Frozen
* Unmoving
Synonyms emphasizing lack of feeling:
* Cold
* Distant
* Aloof
* Indifferent
Synonyms emphasizing lack of communication:
* Mute
* Silent
* Unspeaking
The best synonym for "expressionless" depends on the context of your writing.