For general excellence:
* Ideal
* Flawless
* Immaculate
* Faultless
* Exemplary
* Supreme
* Unsurpassed
For completeness:
* Whole
* Complete
* Total
For accuracy:
* Precise
* Exact
For happiness:
* Blissful
* Ecstatic
For beauty:
* Stunning
* Gorgeous
* Magnificent
For specific situations:
* Optimal (for best possible outcome)
* Ultimate (for the highest level)
The best synonym will depend on the specific context and the nuance you want to convey.