General:
* Assured
* Self-assured
* Bold
* Brave
* Certain
* Positive
* Self-possessed
* Unwavering
* Sure
* Optimistic
* Trusting
Formal:
* Self-reliant
* Composed
* Resolute
* Unflappable
Informal:
* Cool
* Chill
* Easygoing
* At ease
Specific to certain contexts:
* Self-believing (referring to belief in one's abilities)
* Sanguine (referring to optimism)
* Arrogant (referring to excessive confidence)
The best word to use will depend on the specific situation and the tone you want to convey.