* Pentad: A group of five.
* Pentameter: A line of poetry with five metrical feet.
* Pentagram: A five-pointed star.
* Pentathlon: An athletic competition consisting of five events.
* Pentavalent: Having a valence of five.
* Pentarchy: A government of five rulers.
* Pentateuch: The first five books of the Hebrew Bible.
* Pentacle: A five-pointed star used in ceremonial magic.
Let me know if you'd like more examples!