Skill and Expertise:
* Skilled
* Competent
* Expert
* Qualified
* Knowledgeable
* Proficient
* Masterful
Work Ethic and Conduct:
* Dedicated
* Diligent
* Reliable
* Efficient
* Conscientious
* Ethical
* Honorable
* Responsible
Appearance and Demeanor:
* Sophisticated
* Polished
* Classy
* Elegant
* Presentable
* Well-dressed
Related to a Job or Occupation:
* Career
* Occupational
* Vocational
* Trade
The best synonym for "professional" will depend on the specific situation and the nuance you want to convey.