Formal:
* Call me when you have a moment.
* Please call me when you have a free moment.
Informal:
* Call me when you have a minute.
* Call me back when you're free.
* Hit me up when you're free.
Texting/Social Media:
* Call me when u have a min.
* Call me back when you're free.
The best option will depend on who you are talking to and how formal you want to be.