For emphasis:
* Ultra-courteous: This emphasizes a very high degree of courtesy.
* Super-courteous: Similar to "ultra-courteous," this emphasizes a high level of courtesy.
For formality:
* Formal-courteous: This emphasizes the polite and formal nature of the courtesy.
For specific contexts:
* Diplomatic-courteous: This implies courtesy used in a diplomatic or political setting.
* Professional-courteous: This implies courtesy used in a professional context.
Other possibilities:
* Exceedingly courteous: This emphasizes a high level of courtesy.
* Eminently courteous: This emphasizes a very high level of courtesy.
Ultimately, the best prefix will depend on the specific context and the desired meaning.