General:
* Repair: A technician repairs electronic devices.
* Maintain: A technician maintains the machinery.
* Service: A technician services the air conditioning unit.
* Troubleshoot: A technician troubleshoots computer problems.
* Install: A technician installs new software.
Specific to a particular field:
* Diagnose: A medical technician diagnoses illnesses.
* Calibrate: A lab technician calibrates instruments.
* Program: A computer technician programs software.
* Weld: A welding technician welds metal parts.
The best verb to use will depend on the specific context and the type of technician you're talking about.