Formal:
* Destined: They were destined to be together.
* Intended: They were intended to be together.
* Ordained: They were ordained to be together.
Informal:
* Supposed: They were supposed to be together.
* Fated: They were fated to be together.
* Bound: They were bound to be together.
Other options:
* Planned: They were planned to be together.
* Expected: They were expected to be together.
The best word will depend on the context and the desired tone of the sentence.