General synonyms:
* Alert
* Mindful
* Observant
* Heedful
* Considerate
* Responsive
* Eager
* Interested
Synonyms emphasizing focus:
* Concentrated
* Engrossed
* Focused
* Intrigued
Synonyms emphasizing listening:
* Earshot
* Hearken
* Listening
Synonyms emphasizing care:
* Caring
* Solicitous
* Thoughtful
Synonyms emphasizing politeness:
* Courteous
* Polite
* Respectful
The best synonym for "attentive" will depend on the specific context.