To emphasize your ability to throw:
* because: "I like to play baseball because I throw a ball very well."
* since: "I like to play baseball since I throw a ball very well."
To indicate that your throwing skill is part of enjoying baseball:
* and: "I like to play baseball and throw a ball very well."
* as I: "I like to play baseball, as I throw a ball very well."
To show a contrast:
* but: "I like to play baseball, but I throw a ball very well." (This emphasizes your skill while implying you're not necessarily the best player overall)
The best option depends on the nuance you want to convey.