* Adjective clauses modify nouns or pronouns. In this case, the clause modifies the noun "they" (implied).
* They answer the question "which ones?" It tells us specifically which "they" are being referred to - the ones who were all comedians.
Example:
"They were all hilarious, who were all comedians."
The adjective clause clarifies which "they" are being discussed. It functions similarly to an adjective, adding descriptive information.