1. "Une heure de l'après-midi" (literally "one hour of the afternoon")
2. "Un heure de l'après-midi" (the same as above, but with a masculine article)
Note: In French, the time of day is often expressed with the masculine article "un" (one) even when referring to a feminine noun like "heure" (hour). This is because "heure" is considered masculine when it refers to a specific time.
Both options are correct and commonly used.