Here are some examples:
* The attorney general (the noun is "attorney", the adjective "general" comes after)
* The heir apparent (the noun is "heir", the adjective "apparent" comes after)
* Anything else (the noun is "anything", the adjective "else" comes after)
Postpositive adjectives are often used:
* To emphasize the adjective: "I've never seen a house so grand!"
* To clarify the noun: "The child alone was playing in the yard."
* To form certain fixed expressions: "court martial, attorney general, heir apparent"
Let me know if you'd like more examples or have any other questions!