General surprise:
* Un-: This prefix emphasizes the unexpectedness of something, as in "unbelievable" or "unforeseen."
* Extra-: This prefix implies something exceeding expectations, as in "extraordinary" or "extravagant."
* Aston-: This prefix suggests a strong sense of wonder or amazement, as in "astonishing" or "astounding."
Negative surprise:
* Dis-: This prefix suggests something unexpected and unwelcome, as in "disappointing" or "disconcerting."
* Un-: This prefix can also imply a negative surprise, as in "unfortunate" or "unwanted."
Positive surprise:
* Delight-: This prefix emphasizes a pleasant surprise, as in "delightful" or "delighted."
* Wonder-: This prefix suggests amazement and wonder, as in "wonderful" or "wondrous."
Ultimately, the best prefix to use will depend on the specific context and the feeling you want to evoke.