General:
* Deliberately
* On purpose
* Purposefully
* Designedly
* Knowingly
* Consciously
With emphasis on planning:
* Premeditatedly
* With forethought
* Calculatedly
With emphasis on malice:
* Maliciously
* Spitefully
* Vindictively
With emphasis on a specific goal:
* With the aim of
* With the intent to
* In order to
The best synonym for "intentionally" will depend on the context of the sentence.