Here are some examples:
* "He talks a good game about being a great basketball player, but he can't even make a free throw."
* "The politician talks a good game about helping the poor, but his policies don't actually do anything to address poverty."
* "She talks a good game about being a good cook, but everything she makes tastes awful."
Essentially, it means someone is good at *talking* about doing something, but they might not be as good at *actually* doing it. It can be used to describe someone who is boastful or who is full of hot air.