General Antonyms:
* Accidental
* Unintentional
* Unwitting
* Involuntary
* Unplanned
* Fortuitous
* Chance
* Coincidental
More Specific Antonyms:
* Careless (if referring to a lack of attention to detail)
* Negligent (if referring to a lack of responsibility)
* Random (if referring to something without a specific goal)
* Unconscious (if referring to something done without awareness)
The best antonym will depend on the specific meaning you're trying to convey.