General:
* Unfriendly
* Hostile
* Cold
* Aloof
* Unwelcoming
* Unkind
* Rude
* Aggressive
More specific:
* Antagonistic (showing active opposition)
* Averse (having a strong dislike)
* Bitter (having a strong feeling of resentment)
* Confrontational (likely to cause arguments)
* Distant (not close or familiar)
* Formal (not casual or informal)
* Reserved (slow to reveal emotions)
The best antonym will depend on the specific situation.