For physical wincing:
* Grinning: Smiling broadly, often with pleasure or amusement.
* Beaming: Smiling radiantly, expressing happiness.
* Relaxing: Releasing tension and easing discomfort.
For emotional wincing:
* Enjoying: Experiencing pleasure or satisfaction.
* Relishing: Taking great pleasure in something.
* Embracing: Accepting something willingly and enthusiastically.
The best antonym will depend on the specific context in which "wincing" is used.