Here are some examples:
* Who is coming to the party?
* Who wrote that book?
* I know who you are.
"Who" can also be used as the object of a verb, but in this case, it would be followed by a preposition like "to" or "for":
* The book was written by who? (incorrect)
* The book was written by whom? (correct)
Let me know if you have any other questions!