For "relating to administration":
* Operational
* Practical
* Technical
* Hands-on
* Creative (if emphasizing lack of structure)
For "concerned with managing, organizing, or controlling":
* Unstructured
* Free-flowing
* Spontaneous
* Unorganized
* Disorganized
For "bureaucratic":
* Informal
* Independent
* Unregulated
* Free
Ultimately, the best antonym will depend on the specific context of your sentence.