General politeness:
* Polite
* Courteous
* Respectful
* Considerate
* Gracious
* Civil
* Manners
Other words related to being kind and caring:
* Kind
* Gentle
* Compassionate
* Empathetic
* Thoughtful
* Helpful
* Friendly
Words that describe positive interactions:
* Pleasant
* Agreeable
* Cordial
* Warm
* Welcoming
Words that suggest good communication:
* Clear
* Direct
* Open
* Honest
* Understanding
The best word to use will depend on the specific situation and what you are trying to convey.