Here are some possibilities:
* Direct opposite in time: Hier (French for "yesterday")
* Opposite in meaning, referring to the past: Aujourd'hui (French for "today")
* Opposite in meaning, referring to the present: Maintenant (French for "now")
* Opposite in meaning, referring to a hypothetical future: Jamais (French for "never")
The best opposite for "Demain" really depends on the specific context of your sentence.