* Adjective: Describing a state of being by oneself. Example: "She felt alone in the crowd."
* Adverb: Modifying a verb, adjective, or another adverb, indicating a state of isolation. Example: "He walked alone through the forest."
* Noun: Referring to the state of being alone. Example: "He preferred the alone to the company of others."
The most common usage is as an adjective, but the other possibilities exist depending on the context.