* radio: ra-di-o (The "o" is at the end of the open syllable "di".)
* volcano: vol-ca-no (The "o" is at the end of the open syllable "ca".)
* Savior: Sa-vi-or (The "o" is at the end of the open syllable "vi".)
* nature: na-ture (The "o" is at the end of the open syllable "tu".)
* unable: un-a-ble (The "o" is at the end of the open syllable "a".)
In summary, the "o" is at the end of an open syllable in all of the words you listed.