Onomatopoeia:
* Pfft
* Phfft
* Hmph
* Shhh (sometimes used to indicate a more forceful dismissal)
Descriptive words:
* Scoff
* Snort
* Huff
* Blow
* Exhale
The best spelling depends on the context and the specific sound you want to convey. For example, "pfft" is more appropriate for a quick and light puff of air, while "hmph" suggests a more heavy and dismissive exhale.
You can also use a combination of these options, for example, "He gave a dismissive pfft and walked away."