To emphasize the object itself: REfrigerator
To emphasize the cooling function: ReFRIgerator
To distinguish it from something else: Refrigerator, not the freezer.
You can also stress the word differently depending on the context of the sentence.
For example:
"We need to buy a new refrigerator." (Stressing "new")
"The refrigerator is making a strange noise." (Stressing "refrigerator")
Ultimately, how you stress "refrigerator" depends on what you want to communicate.