* Chant is a broader term, encompassing any type of sung liturgical music, including Gregorian chant, Byzantine chant, and other forms.
* Plainsong specifically refers to Gregorian chant, the official liturgical music of the Roman Catholic Church.
Therefore, plainsong is a type of chant, but not all chant is plainsong.
Think of it this way:
* Chant: Umbrella term for all sung liturgical music
* Plainsong: Specific type of chant, like Gregorian chant
It's like saying "car" and "Ford." All Fords are cars, but not all cars are Fords.