Formal:
* À cinq heures (literally "at five hours") - This is the most common and formal way to say it.
Informal:
* À cinq heures précises (literally "at five o'clock sharp") - This is more precise and can be used when you need to emphasize the exact time.
* Cinq heures pile (literally "five o'clock on the dot") - This is a more casual and informal way to say it.
Other options:
* À cinq heures du matin (at five o'clock in the morning)
* À cinq heures du soir (at five o'clock in the evening)
The best option depends on the context and the level of formality required.