To clarify, could you please tell me what specific vowel rule you're thinking of?
For example, are you thinking about:
* The "short vowel" rule (where a single vowel letter usually represents a short vowel sound)?
* The "long vowel" rule (where a vowel letter often has a long vowel sound when followed by a silent "e")?
* The "vowel digraph" rule (where two vowel letters are used to represent a single vowel sound)?
Once you tell me which rule you're interested in, I can give you examples of words where it doesn't apply!