Simple Compounds:
* Headache: A pain in the head.
* Headband: A band worn around the head.
* Headrest: A support for the head.
* Headwind: A wind blowing against the direction of travel.
* Headlight: A light at the front of a vehicle.
* Headlong: With the head foremost.
* Headstrong: Determined to have one's own way.
* Headwaters: The source of a river.
More Complex Compounds:
* Head-on: Directly facing.
* Head-to-head: In direct competition.
* Head-scratcher: A puzzling situation.
* Head-hunter: A person who recruits employees for a company.
These are just a few examples, and there are many more possibilities depending on the context.