Here are some synonyms for extemporaneous:
* Impromptu
* Unscripted
* Off-the-cuff
* Ad-libbed
* Unrehearsed
Here's how the word is used in a sentence:
* The comedian's extemporaneous jokes had the audience roaring with laughter.
* She gave an extemporaneous speech at the conference, surprising everyone with her eloquence.
Note: Extemporaneous can also be used to describe something that is temporary or provisional.