Here's why:
* "Immaterial" already expresses a state or quality. It means "not important" or "not relevant." Adding "-ness" would be redundant.
* "-ness" typically forms nouns from adjectives. While "immaterial" is an adjective, it already functions as a noun in some contexts.
Instead of "immaterialness," you can use synonyms like:
* Irrelevance
* Unimportance
* Triviality
* Unsignificance
These words convey the same meaning as "immaterialness" but are grammatically correct and avoid the awkwardness of adding "-ness" to a word that already implies a quality.