For a group of musicians:
* Band
* Orchestra
* Choir
* Group
* Company
For a group of actors:
* Cast
* Company
* Troupe
For a group of people in general:
* Group
* Team
* Collective
* Assembly
* Gathering
For a collection of items:
* Set
* Collection
* Assortment
* Suit
For a coordinated outfit:
* Outfit
* Costume
* Wardrobe
* Attire
It's important to consider the specific meaning of "ensemble" in the context you're using it to choose the most appropriate synonym.