Here are some options depending on the context:
General:
* A collection of libraries
* A system of libraries
* A network of libraries
More specific:
* A chain of libraries (if they're owned by the same organization)
* A consortium of libraries (if they collaborate)
You could also use a more general collective noun for buildings, like:
* A cluster of libraries
* A row of libraries
Ultimately, the best collective noun to use depends on the specific situation and what you want to emphasize.