"Navigate" is a complete word in itself, meaning "to plan and direct a course of action."
However, you can use related words with prefixes, such as:
* Circumnavigate: to sail or travel all the way around something, especially the Earth.
* Internavigate: to navigate between two or more points.
* Prenavigate: to plan a course of action before navigating.
* Re-navigate: to navigate again.
Let me know if you'd like more examples or have other word combinations in mind!