* AN - This pair has "A" between the letters.
* NS - This pair does not have "A" between the letters.
* SW - This pair does not have "A" between the letters.
* WE - This pair does not have "A" between the letters.
* ER - This pair does not have "A" between the letters.
Therefore, there is only one pair of letters in the word "ANSWER" that has "A" between them: AN.