Here's why:
* Preposition: The word "on" is a preposition, indicating the location or position of something.
* Object of the Preposition: The phrase "the envelope" follows the preposition "on" and acts as the object of the preposition.
* Complete Phrase: Together, "on" and "the envelope" form a prepositional phrase, modifying the verb "put".
The prepositional phrase tells us where the stamp is being placed.