A dictionary entry usually indicates the part of speech for a word. However, without seeing the specific dictionary entry, it's impossible to say for sure.
However, "vestibule" is most commonly used as a noun. It refers to:
* A small entrance hall or lobby.
* A small space or chamber at the entrance of a building, especially one leading to a larger room.
Let me know if you have a specific dictionary entry you'd like me to look at!