Here's why:
* "Although" is a subordinating conjunction. It introduces a dependent clause that needs an independent clause to complete the thought.
* Dependent clauses usually come *after* the independent clause. For example:
* Although it was raining, I went for a walk.
* Independent clause: I went for a walk.
* Dependent clause: Although it was raining.
* When the dependent clause comes first, you usually put a comma after it.
Let's look at some examples:
* Correct: Although it was raining, I went for a walk.
* Incorrect: Although, it was raining, I went for a walk.
Key takeaway: No comma after "Although" when it begins a sentence.