There isn't a comparative form of "joyous" in the same way we have "bigger" and "biggest".
Here are some ways to express different levels of joy:
More joyful or more joyous than: This implies a higher degree of joy than something else.
Most joyful: This would be used to describe the highest level of joy possible.
Extremely joyful: This emphasizes the intensity of the joy.
Overjoyed: This is another way to express a high level of joy, often used in a more formal context.