There's no comparative form of "unpleasant" because it's already expressing a high degree of the quality of being unpleasant.
If you want to express a greater degree of unpleasantness, you can use adverbs like:
* More unpleasant
* Extremely unpleasant
* Highly unpleasant
* Terribly unpleasant
* Utterly unpleasant
You can also use synonyms with a stronger meaning, such as:
* Awful
* Disgusting
* Repulsive
* Horrible
* Abhorrent