General:
* Preface
* Foreword
* Prologue
* Opening
* Preamble
* Introductory chapter
* Starting point
More specific:
* Author's note: Often found at the beginning of fiction books.
* Acknowledgements: Expresses gratitude to people who helped with the book.
* Dedication: Addresses the book to someone.
The best word to use depends on the specific context and the type of book.