1. re-ha-bil-i-tate
This is the more common and straightforward way to syllabicate the word, following the rules of syllable division.
2. re-ha-bi-li-tate
This syllabification, while less common, is also acceptable. It focuses on separating the prefix "re-" from the root word "habilitate."
Both ways of syllabication are correct and depend on the context and the specific pronunciation you are using.