Here are some examples:
Specific Person:
* Justin Trudeau (Canadian Prime Minister)
* Anthony Albanese (Australian Prime Minister)
* Liz Truss (former British Prime Minister)
Specific Position:
* The Prime Minister (if referring to a specific country, you can add the country name after, e.g., "The Prime Minister of Canada")
* The Premier (if referring to a specific region, you can add the region's name after, e.g., "The Premier of Alberta")
General Term:
* Premier (when used as a general title, it's not usually capitalized)
So, the best way to decide on a proper noun is to consider the specific situation and who you're referring to.